By Pedro J. Pérez (Ed.),Pedro J. Pérez
Over the previous decade, a lot learn attempt has been dedicated to the layout and synthesis of latest reagents and catalysts which can effect carbon-hydrogen bond activation, often end result of the prospect that C−H activation may possibly let the conversion of inexpensive and considerable alkanes into invaluable functionalized natural compounds.
Alkane C-H Activation by way of Single-Site steel Catalysis provides the present state of the art improvement within the catalytic structures for the catalytic trans-formations of alkanes below homogeneous stipulations. bankruptcy 1 deals a finished precis of the most discoveries discovered to date. bankruptcy 2 reports the so-called electrophilic activation, initiated by means of Shulpín within the overdue 60s, and the bottom for the Catalytica system. bankruptcy three examines the catalytic borylation of alkanes, chanced on by way of Hartwig, while bankruptcy four presents an up to date imaginative and prescient of the alkane dehydrogenation response. bankruptcy five covers the oxygenation of C-H bonds, a box of huge curiosity with bioinorganic im-plications, and eventually bankruptcy 6 offers the functionalization of alkane C-H bonds through carbene or nitrene insertion.
The historical past of C-H bond activation, and the present study defined during this ebook, spotlight the present examine and current the reader with an outlook of this box which is still explored through an more and more visionary and enthusiastic workforce of natural, organometallic, organic and actual chemists.
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